|
週次 |
日期 |
單元主題 |
|
第1週 |
|
Definitions of system, work, heat; first law of thermodynamics; disorder, and entropy. |
|
第2週 |
|
Postulates in thermodynamics; intensive and extensive variables; kinetic theory of ideal gases; |
|
第3週 |
|
Physical meaning of derivatives of internal energy under various constraints (pressure, temperature, chemical potential); free expansion of ideal and real gases; definition of enthalpy and heat capacities. |
|
第4週 |
|
Adiabatic Processes; calorimetry; calculation of enthalpy changes; differential scanning calorimetry |
|
第5週 |
|
Second Law; Isothermal expansion of an ideal gas; reversible processes; Clausius theorem; |
|
第6週 |
|
Calculation of entropy change under various changes in state; reversible adiabatic processes; entropy changes in irreversible processes; |
|
第7週 |
|
Recitation |
|
第8週 |
|
Mid-term exam; |
|
第9週 |
|
Gibbs energy; Gibbs-Helmholtz equation; effects of temperature and pressure on G; activities; general equilibrium expression; van't Hoff equation |
|
第10週 |
|
Phase diagram of water; chemical potential surface; temperature depdencen of Gibbs energy; latent heat |
|
第11週 |
|
Calusius-Clapeyron equation; depression of melting point; thermodynamics of phase separation |
|
第12週 |
|
Nucleation and spinodal decomposition; driving force of nucleation; liquid-liquid phase diagram; monotectics; lever rule |
|
第13週 |
|
Eutectics; mesophase; Krafft point |
|
第14週 |
|
Electrical double layer; Zeta potential; Debye length; potential across membranes; energetics of transport across membranes |
|
第15週 |
|
Average number of protons bound by phosphate ions; determination of dissociation constant; pH dependence of enzyme catalyzed reactions; coupling of reactions; binding of oxygen |
|
第16週 |
|
Final exam |